Highly Reactive Metal-Nitrogen Bond Induced C-H Bond Activation and Azametallacycle Formation

被引：26
|
作者：
Panda, Tarun K. [1 ]
Tsurugi, Hayato [1 ]
Pal, Kuntal [1 ]
Kaneko, Hiroshi [1 ]
Mashima, Kazushi [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Osaka 5608531, Japan
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 01期
关键词：
CATALYZED INTRAMOLECULAR HYDROAMINATION/CYCLIZATION; SECONDARY-AMINES; N-H; SUBSTITUTED GUANIDINES; ZIRCONOCENE COMPLEXES; UNACTIVATED OLEFINS; ALLYLIC AMINES; TANTALUM; ALKENES; HYDROAMINOALKYLATION;
D O I：
10.1021/om901027v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A group 4 metal-nitrogen bond inserted into the carbon-nitrogen double bond of carbodiimides and alpha-diimines to afford guanidinate and amido-imino ligand supported group 4 metal complexes, respectively. Metal-nitrogen mediated C-H bond activation alpha to the nitrogen atom led to the formation of azametallacycle complexes.
引用
收藏
页码：34 / 37
页数：4
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