Highly Reactive Metal-Nitrogen Bond Induced C-H Bond Activation and Azametallacycle Formation

被引：26

作者：

Panda, Tarun K. ^{[1
]}

Tsurugi, Hayato ^{[1
]}

Pal, Kuntal ^{[1
]}

Kaneko, Hiroshi ^{[1
]}

Mashima, Kazushi ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Osaka 5608531, Japan

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 01期

关键词：

CATALYZED INTRAMOLECULAR HYDROAMINATION/CYCLIZATION; SECONDARY-AMINES; N-H; SUBSTITUTED GUANIDINES; ZIRCONOCENE COMPLEXES; UNACTIVATED OLEFINS; ALLYLIC AMINES; TANTALUM; ALKENES; HYDROAMINOALKYLATION;

D O I：

10.1021/om901027v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A group 4 metal-nitrogen bond inserted into the carbon-nitrogen double bond of carbodiimides and alpha-diimines to afford guanidinate and amido-imino ligand supported group 4 metal complexes, respectively. Metal-nitrogen mediated C-H bond activation alpha to the nitrogen atom led to the formation of azametallacycle complexes.

引用

页码：34 / 37

页数：4

共 50 条

[1] C-H Bond Activation Induced by Group 4 Metal Nitrogen Bond to Form Acetimidamide Metal Complexes
Bhattacharjee, Jayeeta
Panda, Tarun K.
CHEMISTRYSELECT, 2017, 2 (11): : 3231 - 3235
[2] ACTIVATION OF C-H BOND WITH METAL-COMPLEXES
SHILOV, AE
SHULPIN, GB
USPEKHI KHIMII, 1990, 59 (09) : 1468 - 1491
[3] Advances in C-CN Bond Formation via C-H Bond Activation
Ping, Yuanyuan
Ding, Qiuping
Peng, Yiyuan
ACS CATALYSIS, 2016, 6 (09): : 5989 - 6005
[4] A versatile ruthenium catalyst for C-C bond formation by C-H bond activation
Martinez, Remi
Chevalier, Reynald
Darses, Sylvain
Genet, Jean-Pierre
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) : 8232 - 8235
[5] THE TRANSITION METAL-NITROGEN MULTIPLE BOND
DEHNICKE, K
STRAHLE, J
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (05): : 413 - 426
[6] Metal mediated regioselective C-N bond formation via tandem C-H and N-H bond activation
Marchetti, Louis
Kantak, Abhishek
DeBoef, Brenton
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[7] Metal-catalysed C-H bond activation and borylation
Bisht, Ranjana
Haldar, Chabush
Hassan, Mirja Md Mahamudul
Hoque, Md Emdadul
Chaturvedi, Jagriti
Chattopadhyay, Buddhadeb
CHEMICAL SOCIETY REVIEWS, 2022, 51 (12) : 5042 - 5100
[8] C-H bond activation in the formation of an osmium(IV) metallacycle
Koch, JL
Shapley, PA
ORGANOMETALLICS, 1999, 18 (05) : 814 - 816
[9] Kinetic consequences of oxygen and carbon in C-H bond cleavage and C-H bond formation on transition metal and alloy clusters
Tu, Weifeng
Lachkov, Petar
Chin, Ya-Huei
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[10] A Highly Reactive Rhodium(I) Boryl Complex as a Useful Tool for C-H Bond Activation and Catalytic C-F Bond Borylation
Teltewskoi, Michael
Panetier, Julien A.
Macgregor, Stuart A.
Braun, Thomas
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (23) : 3947 - 3951

← 1 2 3 4 5 →