Cp2Zr(η2-benzocyclobutadiene)(PMe3), a rare η2-cyclobutadiene complex

被引：34
|
作者：
Ramakrishna, TVV [1 ]
Lushnikova, S [1 ]
Sharp, PR [1 ]
机构：
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 26期
关键词：
D O I：
10.1021/om020829h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Thermal decomposition of Cp2ZrMe(1-bromobenzocyclobutenyl) yields the eta(2)-cyclobutadiene complex Cp2Zr(eta(2)-benzocyclobutadiene)(PMe3), which cycloadds alkenes, nitriles, and t-BuNC, in the last case giving a novel diamino-Dewar-naphthalene complex.
引用
收藏
页码：5685 / 5687
页数：3
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