Cp2Zr(η2-benzocyclobutadiene)(PMe3), a rare η2-cyclobutadiene complex

被引：34

作者：

Ramakrishna, TVV ^{[1
]}

Lushnikova, S ^{[1
]}

Sharp, PR ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 26期

关键词：

D O I：

10.1021/om020829h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal decomposition of Cp2ZrMe(1-bromobenzocyclobutenyl) yields the eta(2)-cyclobutadiene complex Cp2Zr(eta(2)-benzocyclobutadiene)(PMe3), which cycloadds alkenes, nitriles, and t-BuNC, in the last case giving a novel diamino-Dewar-naphthalene complex.

引用

页码：5685 / 5687

页数：3

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