Copper(I)-Catalyzed Synthesis of Polysubstituted Furans from Alkynoates and 1,3-Dicarbonyl Compounds in the Presence of Oxygen

被引:39
|
作者
Yan, Rulong [1 ]
Huang, Jing [1 ]
Luo, Jia [1 ]
Wen, Ping [1 ]
Huang, Guosheng [1 ]
Liang, Yongmin [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
polysubstituted furans; oxidant; copper catalysis; oxygen; HIGHLY SUBSTITUTED FURANS; ONE-POT SYNTHESIS; CATALYZED CYCLOISOMERIZATION; 2-(1-ALKYNYL)-2-ALKEN-1-ONES; MIGRATION; OXIDATION; ANALOGS; KETONES; SYSTEM;
D O I
10.1055/s-0029-1219778
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel and straightforward synthesis of polysubstituted furans was achieved easily from the oxidative cyclization of 1,3-dicarbonyl compound and alkynoate catalyzed by CuI in the presence of O-2.
引用
收藏
页码:1071 / 1074
页数:4
相关论文
共 50 条
  • [41] Synthesis of (1,3-adamantylene)bis-1,3-dicarbonyl compounds
    A. A. Turmasova
    V. V. Konshin
    Dzh. N. Konshina
    Russian Journal of General Chemistry, 2014, 84 : 1273 - 1276
  • [42] Synthesis of (1,3-adamantylene)bis-1,3-dicarbonyl compounds
    Turmasova, A. A.
    Konshin, V. V.
    Konshina, Dzh. N.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2014, 84 (07) : 1273 - 1276
  • [43] Bulky thioureas as new ligands for gold(I)-catalyzed cyclization of acetylenic 1,3-dicarbonyl compounds
    Pan, Jie-Hui
    Yang, Min
    Gao, Qiang
    Zhu, Nian-Yong
    Yang, Dan
    SYNTHESIS-STUTTGART, 2007, 16 (16): : 2539 - 2544
  • [44] COBALT(II) CATALYZED ALLYLATION OF 1,3-DICARBONYL COMPOUNDS WITH ALLYL ACETATES
    BHATIA, B
    REDDY, MM
    IQBAL, J
    TETRAHEDRON LETTERS, 1993, 34 (39) : 6301 - 6304
  • [45] TfOH-Catalyzed Reaction of Bispropargyl Alcohols with 1,3-Dicarbonyl Compounds
    Teng, Qinghu
    Mo, Shikun
    Pan, Jiankun
    Wu, Na
    Wang, Hengshan
    Pan, Yingming
    SYNTHESIS-STUTTGART, 2016, 48 (03): : 455 - 461
  • [46] Alkylation of 1,3-Dicarbonyl Compounds and Their Analogues with 2-Halomethyl(ethoxycarbonyl)(diethoxyphosphorylmethyl)furans
    Pevzner, L. M.
    Ponyaev, A. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2020, 90 (08) : 1453 - 1465
  • [47] Alkylation of 1,3-Dicarbonyl Compounds and Their Analogues with 2-Halomethyl(ethoxycarbonyl)(diethoxyphosphorylmethyl)furans
    L. M. Pevzner
    A. I. Ponyaev
    Russian Journal of General Chemistry, 2020, 90 : 1453 - 1465
  • [48] Mild α-halogenation reactions of 1,3-dicarbonyl compounds catalyzed by Lewis acids
    Yang, D
    Yan, YL
    Lui, B
    JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (21): : 7429 - 7431
  • [49] A general and efficient iron-catalyzed benzylation of 1,3-dicarbonyl compounds
    Kischel, Jette
    Mertins, Kristin
    Michalik, Dirk
    Zapf, Alexander
    Beller, Matthias
    ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (06) : 865 - 870
  • [50] Molecular iodine catalyzed coupling reactions of indole with 1,3-dicarbonyl compounds
    Shrinivas S. Kottawar
    Shaphi A. Siddiqui
    Shrikant S. Pendalwar
    Wamanrao N. Jadhav
    Sudhakar R. Bhusare
    Research on Chemical Intermediates, 2014, 40 : 2929 - 2934