Room Temperature Reduction of CO2 to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane

被引：485

作者：

Menard, Gabriel ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 06期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FREE CATALYTIC-HYDROGENATION; CARBON-DIOXIDE; ACTIVATION; REACTIVITY; B(C6F5)(3); ALUMINUM; IMINES; SYSTEM; H-2;

D O I：

10.1021/ja9104792

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AlX3 (X = Cl or Br) and PMes(3) (Mes = 2,4,6-C6H2Me3) react to form weak Lewis adducts but also react with CO2 to give Mes(3)P(CO2)(AlX3)(2) (X = Cl; Br). These species react rapidly with excess ammonia borane at room temperature to give CH3OH upon quenching with water.

引用

页码：1796 / +

页数：4

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