Al(H2PO4)3 as an Efficient and Reusable Catalyst for One-pot Three-component Synthesis of α-Amino Phosphonates under Solvent-free Conditions

被引：31

作者：

Maghsoodlou, Malek Taher ^{[1
]}

Habibi-Khorassani, Sayyed Mostafa ^{[1
]}

Heydari, Reza ^{[1
]}

Hazeri, Nourollah ^{[1
]}

Sajadikhah, Seyed Sajad ^{[1
]}

Rostamizadeh, Mohsen ^{[1
]}

机构：

[1] Univ Sistan & Baluchestan, Dept Chem, Fac Sci, Zahedan, Iran

来源：

CHINESE JOURNAL OF CHEMISTRY | 2010年 / 28卷 / 02期

关键词：

alpha-amino phosphonate; Al(H2PO4)(3); heterogeneous catalyst; aldehyde; trialkyl phosphite; ENVIRONMENTALLY FRIENDLY PREPARATION; ORGANIC PHOSPHORUS-COMPOUNDS; STEREOSELECTIVE-SYNTHESIS; ACID; AMINOPHOSPHONATES; INHIBITORS; PHOSPHITE; ALDEHYDES; WELL;

D O I：

10.1002/cjoc.201090067

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of alpha-amino phosphonates is described under solvent-free conditions at 100 degrees C from reaction between aldehydes and amines in the presence of trialkyl phosphites using Al(H2PO4)(3) as an efficient and reusable heterogeneous catalyst. The advantages of this procedure are short reaction time, flexibility and having high to excellent yields.

引用

页码：285 / 288

页数：4

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