1,1-Carboboration to tellurium-boron intramolecular frustrated Lewis pairs

被引：26
|
作者：
Tsao, Fu An [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 01期
关键词：
FREE HYDROGEN ACTIVATION; 1,1-ORGANOBORATION; DERIVATIVES; ACID; ION; TRIORGANOBORANES; TELLUROPHENES; BROMINATION; REACTIVITY; COMPLEXES;
D O I：
10.1039/c4dt03241a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tellurium acetylide Ph(CH2)(2)TeCCPh reacts with boranes via 1,1-carboboration to give a series of borylated vinyl telluroethers. The product Ph(CH2)(2)TeC(Ph)C(C6F5) B(C6F5)(2) reacts with phenylacetylene and iodine to give novel tellurium-boron heterocyclic compounds.
引用
收藏
页码：71 / 74
页数：4
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