1,1-Carboboration to tellurium-boron intramolecular frustrated Lewis pairs

被引：26
|
作者：
Tsao, Fu An [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 01期
关键词：
FREE HYDROGEN ACTIVATION; 1,1-ORGANOBORATION; DERIVATIVES; ACID; ION; TRIORGANOBORANES; TELLUROPHENES; BROMINATION; REACTIVITY; COMPLEXES;
D O I：
10.1039/c4dt03241a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tellurium acetylide Ph(CH2)(2)TeCCPh reacts with boranes via 1,1-carboboration to give a series of borylated vinyl telluroethers. The product Ph(CH2)(2)TeC(Ph)C(C6F5) B(C6F5)(2) reacts with phenylacetylene and iodine to give novel tellurium-boron heterocyclic compounds.
引用
收藏
页码：71 / 74
页数：4
相关论文
共 50 条
  • [1] Functionalization of Intramolecular Frustrated Lewis Pairs by 1,1-Carboboration with Conjugated Enynes
    Feldmann, Andreas
    Kehr, Gerald
    Daniliuc, Constantin G.
    Mueck-Lichtenfeld, Christian
    Erker, Gerhard
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (35) : 12456 - 12464
  • [2] 1,1-Carboboration
    Kehr, Gerald
    Erker, Gerhard
    CHEMICAL COMMUNICATIONS, 2012, 48 (13) : 1839 - 1850
  • [3] Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair
    Liedtke, Rene
    Scheidt, Felix
    Ren, Jinjun
    Schirmer, Birgitta
    Cardenas, Allan Jay P.
    Daniliuc, Constantin G.
    Eckert, Hellmut
    Warren, Timothy H.
    Grimme, Stefan
    Kehr, Gerald
    Erker, Gerhard
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (25) : 9014 - 9027
  • [4] Borole Formation by 1,1-Carboboration
    Ge, Fang
    Kehr, Gerald
    Daniliuc, Constantin G.
    Erker, Gerhard
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (01) : 68 - 71
  • [5] Preparation of Dithienylphospholes by 1,1-Carboboration
    Moebus, Juri
    Galstyan, Anzhela
    Feldmann, Andreas
    Daniliuc, Constantin G.
    Froehlich, Roland
    Strassert, Cristian A.
    Kehr, Gerald
    Erker, Gerhard
    CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (37) : 11883 - 11893
  • [6] A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair
    Chen, Chaohuang
    Daniliuc, Constantin G.
    Mueck-Lichtenfeld, Christian
    Kehr, Gerald
    Erker, Gerhard
    CHEMICAL COMMUNICATIONS, 2020, 56 (62) : 8806 - 8809
  • [7] Trisubstituted Boroles by 1,1-Carboboration
    Ge, Fang
    Kehr, Gerald
    Daniliuc, Constantin G.
    Mueck-Lichtenfeld, Christian
    Erker, Gerhard
    ORGANOMETALLICS, 2015, 34 (17) : 4205 - 4208
  • [8] Phosphole formation by 1,1-carboboration - reactions of bis-alkynyl phosphanes with a frustrated P/B Lewis pair
    Klose, Annika
    Kehr, Gerald
    Daniliuc, Constantin G.
    Erker, Gerhard
    DALTON TRANSACTIONS, 2016, 45 (05) : 2023 - 2030
  • [9] 1,1-Carboboration Route to Substituted Naphthalenes
    Liedtke, Rene
    Harhausen, Marcel
    Froehlich, Roland
    Kehr, Gerald
    Erker, Gerhard
    ORGANIC LETTERS, 2012, 14 (06) : 1448 - 1451
  • [10] Reactions of Boroles Formed by 1,1-Carboboration
    Ge, Fang
    Kehr, Gerald
    Daniliuc, Constantin G.
    Erker, Gerhard
    ORGANOMETALLICS, 2015, 34 (01) : 229 - 235
12345