Metal complexes of 3-thiophene carboxamides containing a pyridine ring

被引：6
|
作者：
Howell, S. Jarrett [1 ]
Day, Cynthia S. [1 ]
Noftle, Ronald E. [1 ]
机构：
[1] Wake Forest Univ, Dept Chem, Winston Salem, NC 27109 USA
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 08期
关键词：
copper; zinc; cobalt; complexes; crystal structures; infrared; synthesis; visible spectroscopy; electrochemistry;
D O I：
10.1016/j.ica.2007.01.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complexes of Zn(II), Cu(II) and Co(II) with either N-(2-methylpyridyl)-3-thienyl-alkyl-carboxamide or N-(2-pyridyl)-3-thienylalkylcarboxamide groups have been prepared and characterized. Crystal structures of ten new complexes are reported and discussed. N-(2-Methylpyridyl)-3-thienyl-alkyl-carboxamide exhibits both uni- and bidentate behavior. With all ligands, bidentate complexation is through the carbonyl oxygen and pyridine nitrogen atoms (O, N) and the amide nitrogen atom remains protonated. The electrochemical behavior and the infrared spectra of selected complexes are discussed. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：2669 / 2680
页数：12
相关论文
共 50 条
  • [11] QUATERNARY SALTS OF PYRIDINE-3-CARBOXAMIDES
    ZIENTY, MF
    JOURNAL OF THE AMERICAN PHARMACEUTICAL ASSOCIATION-SCIENTIFIC EDITION, 1948, 37 (03): : 99 - 101
  • [12] Synthesis, crystal structure and characterization of 3-thiophene aldehyde thiosemicarbazone and its complexes with cobalt(II), nickel(II) and copper(II)
    Alomar, Kusai
    Khan, Mustayeen A.
    Allain, Magali
    Bouet, Gilles
    POLYHEDRON, 2009, 28 (07) : 1273 - 1280
  • [13] METAL-COMPLEXES WITH MACROCYCLIC LIGANDS .10. METAL COMPLEXATION KINETICS OF 2 N4-MACROCYCLES CONTAINING A PYRIDINE RING
    SCHULTZGRUNOW, P
    KADEN, TA
    HELVETICA CHIMICA ACTA, 1978, 61 (07) : 2291 - 2296
  • [14] Metal complexes of pyridine-3-carboxyaldehyde thiosemicarbazone
    Singh, C
    Parwana, HK
    Singh, G
    Jolly, RS
    ASIAN JOURNAL OF CHEMISTRY, 2000, 12 (01) : 1 - 8
  • [15] Schiff base and metal(II) complexes containing thiophene-3-carboxylate: Synthesis, characterization and antioxidant activities
    Bingol, Mustafa
    Turan, Nevin
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1205
  • [16] Development of antimycobacterial tetrahydrothieno[2,3-c]pyridine-3-carboxamides and hexahydrocycloocta[b]thiophene-3-carboxamides: Molecular modification from known antimycobacterial lead
    Nallangi, Radhika
    Samala, Ganesh
    Sridevi, Jonnalagadda Padma
    Yogeeswari, Perumal
    Sriram, Dharmarajan
    EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2014, 76 : 110 - 117
  • [17] Poly (3-thiophene acetic acid)/chitosan self assembled bilayers.
    Mello, SV
    Constantine, CA
    Dupont, A
    Cao, XH
    Santos, DS
    Oliveira, ON
    Strixino, FT
    Pereira, EC
    Leblanc, RM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U519 - U519
  • [18] Electrical Conductivity and Optical Properties of Ploly(3-thiophene boronic acid) Organic Semiconductor
    Yakuphanoglu, Fahrettin
    Senkal, B. Filiz
    POLYMER ENGINEERING AND SCIENCE, 2009, 49 (04): : 722 - 726
  • [19] Pathways for cyclopropylidene ring opening in pyridine-containing ruthenium alkylidene complexes.
    Vilain, JM
    Mason, MH
    Gile, MA
    Mason, SL
    Heppert, J
    Carlson, RG
    Powell, DR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U736 - U737
  • [20] ELECTRONIC-SPECTRA AND IR CHARACTERISTICS OF SOME 2-FURAN-CARBOXAMIDES AND 3-FURAN-CARBOXAMIDES AND 3-THIOPHENE-CARBOXAMIDES
    ALBERGHINA, G
    FISICHELLA, S
    OCCHIPINTI, S
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1980, 36 (04) : 349 - 357
12345