The first pseudo-ternary thiocyanate containing two alkali metals - synthesis and single-crystal structure of LiK2[SCN]3

被引：5

作者：

Reckeweg, Olaf ^{[1
]}

DiSalvo, Francis J. ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2016年 / 71卷 / 02期

关键词：

lithium; potassium; structure elucidation; thiocyanate;

D O I：

10.1515/znb-2015-0175

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A procedure was empirically developed to prepare the compound LiK2[SCN](3), which forms colorless, transparent, very fragile, and extremely hygroscopic thin rectangular plates. Its unique crystal structure was determined by single-crystal X-ray diffraction. LiK2[SCN](3) adopts the orthorhombic space group Pna2(1) (no. 33, Z = 4) with the cell parameters a = 1209.32(9), b = 950.85(9), and c = 849.95(6) pm.

引用

页码：161 / 164

页数：4

共 50 条

[21] Ta3AlC2 and Ta4AlC3 -: Single-crystal investigations of two new ternary carbides of tantalum synthesized by the molten metal technique
Etzkorn, Johannes
Ade, Martin
Hillebrecht, Harald
INORGANIC CHEMISTRY, 2007, 46 (04) : 1410 - 1418
[22] Synthesis and Single-crystal Structure of a One-dimensional Zinc(Ⅱ) Phosphonate: [Zn3(PhPO3)2(PhPO3H)2(Phen)2]n
曹彦宁
张汉辉
黄长沧
张凤利
陈义平
张帅
张春刚
胡进
Chinese Journal of Structural Chemistry, 2009, 28 (01) : 37 - 40
[23] The structure of Ce2Al3Ge4 refined for the first time from single-crystal X-ray diffraction data
Tobash, Paul
Bobev, Svilen
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2021, 77 : 81 - +
[24] Synthesis, crystal growth, and structure of Ta3Al2CoC -: An ordered quarternary cubic η-carbide and the first single crystal study of a η-carbide
Etzkorn, Johannes
Hillebrecht, Harald
JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (06) : 1342 - 1346
[25] New rubidium zinc hydrogen phosphate, Rb2Zn2(HPO4)3:: Synthesis, crystal structure, and 31P single-crystal NMR
Jensen, TR
Hazell, RG
Vosegaard, T
Jakobsen, HJ
INORGANIC CHEMISTRY, 2000, 39 (10) : 2026 - 2032
[26] Synthesis and single-crystal structure of an unusual heptacoordinate cadmium(II) complex, [Cd(medien)(NO3)2] (medien = bis(2-aminoethyl)methylamine)
Mondal, A
Chaudhuri, S
Ghosh, A
Laskar, IR
Chaudhuri, NR
ACTA CHEMICA SCANDINAVICA, 1998, 52 (08): : 1064 - 1067
[27] HYDROTHERMAL SYNTHESIS AND SINGLE-CRYSTAL STRUCTURE OF BARIUM VANADIUM SELENITE HYDRATE Ba(VO2)2(SeO3)2•H2O
Lincoln, F. J.
Kilminster, K. L.
Skelton, B. W.
White, A. H.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2002, 58 : C316 - C316
[28] The Synthesis and Crystal Structure of the First Trinuclear Molybdenum Complex Containing PyS Ligands [Mo3(CO)6(μ-PyS)2(μ3-PyS)2]
石有茂
陆世维
郭和夫
施剑秋
吴锵金
ChineseScienceBulletin, 1994, (03) : 263 - 264
[29] Synthesis and Single-crystal Structure of a One-dimensional Zinc(II) Phosphonate: [Zn3(PhPO3)2(PhPO3H)2(Phen)2]n
Cao Yan-Ning
Zhang Han-Hui
Huang Chang-Cang
Zhang Feng-Li
Chen Yi-Ping
Zhang Shuai
Zhang Chun-Gang
Hu Jin
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (01) : 37 - 40
[30] ALKYLMETAL AND ARYLMETAL COMPOUNDS .36. SYNTHESIS AND STRUCTURE OF [(NA(TMEDA))3][LIPH4], AN ORGANOMETALLIC COMPLEX CONTAINING 2 DIFFERENT ALKALI-METALS
SCHUMANN, U
WEISS, E
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (04): : 584 - 585

← 1 2 3 4 5 →