The first pseudo-ternary thiocyanate containing two alkali metals - synthesis and single-crystal structure of LiK2[SCN]3

被引：5
|
作者：
Reckeweg, Olaf [1 ]
DiSalvo, Francis J. [1 ]
机构：
[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2016年 / 71卷 / 02期
关键词：
lithium; potassium; structure elucidation; thiocyanate;
D O I：
10.1515/znb-2015-0175
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A procedure was empirically developed to prepare the compound LiK2[SCN](3), which forms colorless, transparent, very fragile, and extremely hygroscopic thin rectangular plates. Its unique crystal structure was determined by single-crystal X-ray diffraction. LiK2[SCN](3) adopts the orthorhombic space group Pna2(1) (no. 33, Z = 4) with the cell parameters a = 1209.32(9), b = 950.85(9), and c = 849.95(6) pm.
引用
收藏
页码：161 / 164
页数：4
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