Synthesis of "Clickable" Nano Metal-organic Framework by Generic Postsynthetic Modification Route

被引：13
|
作者：
Yue, Dan [1 ,2 ]
Chen, Dong [1 ]
Zhang, Xin [2 ]
Huang, Yike [2 ]
Wang, Zhenling [1 ]
机构：
[1] Henan Univ Engn, Ctr Anal & Testing, Sch Mat & Chem Engn, Zhengzhou 451191, Henan, Peoples R China
[2] Zhejiang Univ, Sch Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 22期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Postsynthetic modification; Porous materials; Nanocrystalline materials; Metal-organic framework; Click chemistry; SELECTIVE DETECTION; TURN-ON; MOF; CHEMISTRY; CU2+;
D O I：
10.1002/zaac.201900225
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Organic azides have been somewhat popularized due to their pivotal role in the emerging field of "click chemistry". A simple approach has been used for the synthesis of uniform nano Fe-MIL-88B-NH2, and a generic postsynthetic modification route has been developed for the synthesis of azide-modified nano Fe-MIL-88B-N-3. The approach also has been used to synthesize the azide-modified IRMOF-3(-N-3). These new azide-modified Fe-MIL-88B-N-3 nanocrystals hold promising potential for the applications in the fields of "click chemistry", nanotechnology devices and nano composite membranes.
引用
收藏
页码：1303 / 1306
页数：4
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