modification of carbon nanotubes;
Diels-Alder and Sand-Meyer reaction;
catalytic oxidation;
D O I:
10.4028/www.scientific.net/MSF.537-538.623
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
In order to alter the physical/chemical characteristics of multi-walled carbon nanotubes (MWNTs) we modified them by different organic reactions (Diels-Alder and Sand-Meyer reaction, oxidation) and their d properties were characterized by thermogravimetry/mass spectrometry, photoelectron spealterectroscopy, and nuclear magnetic resonance spectroscopy, as well as by dispersion. The results proved that, depending on the groups built in the MWNTs, the modified carbon nanotubes are more dispersible either in polar or apolar solvents and the suspensions are stable for long time. The presence of the substituents in the MWNTs was proved by methods listed above, e.g. high concentration of sulfur was detected when SO3H groups were inserted onto the MWNTs. The enhanced thermal stability of the modified carbon nanotubes allows their further application.
机构:
Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Nanchang Univ, Dept Chem, Nanchang 330047, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Hu, Changyuan
Liao, Hongliu
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机构:
S China Univ Technol, Coll Chem & Energy, Guangzhou 510641, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Liao, Hongliu
Li, Fengyi
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机构:
Nanchang Univ, Dept Chem, Nanchang 330047, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Li, Fengyi
Xiang, Junhuai
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机构:
Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Xiang, Junhuai
Li, Wenkui
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机构:
Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Li, Wenkui
Duo, Shuwang
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机构:
Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China
Duo, Shuwang
Li, Mingsheng
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机构:
Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R ChinaJiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Peoples R China