Di-μ1,1-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)]

被引：3
|
作者：
Li, He-Bing [1 ]
机构：
[1] Xiangnan Univ, Dept Chem & Life Sci, Chenzhou 423000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
MAGNETIC-PROPERTIES; STRUCTURAL-CHARACTERIZATION; AZIDO; COMPLEXES; BRIDGES;
D O I：
10.1107/S1600536810017174
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the centrosymmetric binuclear title complex, [Cu-2(C13H19N2O)(2)(N-3)(2)], the Cu-II atom adopts an elongated CuON4 square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu center dot center dot center dot Cu separation is 3.2365 (3) angstrom. A pair of intramolecular N-H center dot center dot center dot O hydrogen bonds helps to establish the molecular conformation.
引用
收藏
页码：M651 / U529
页数：11
相关论文
共 50 条
  • [41] Mono-, di- and trinuclear copper(II) dioxime complexes; 3-{2-[2-(2-hydroxyimino-1-methylpropylideneamino)ethylamino]ethylimino}butan-2-one oxime
    Kerim Serbest
    Serdar Karaböcek
    İsmail Değirmencioğlu
    Saadettin Güner
    Fatma Kormali
    Transition Metal Chemistry, 2001, 26 : 375 - 379
  • [42] Poly[tetra-μ1,1-azido-bis(μ2-pyrimidine-2-carboxylato)tricopper(II)]
    Zhao, Jiong-Peng
    Liu, Fu-Chen
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M973 - U1045
  • [43] Mono-, di- and trinuclear copper(II) dioxime complexes;: 3-{2-[2-(2-hydroxyimino-1-methylpropylideneamino)ethylamino]ethylimino}butan-2-one oxime
    Serbest, K
    Karaböcek, S
    Degirmencioglu, I
    Güner, S
    Kormali, F
    TRANSITION METAL CHEMISTRY, 2001, 26 (4-5) : 375 - 379
  • [44] Bis[-2-({2-[2-(2-chlorophenoxy)-1-oxidoethylidene]hydrazinylidene}methyl)phenolato]bis[pyridinecopper(II)] methanol disolvate
    Zhao, Ning
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2013, 69 : 348 - +
  • [45] 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate toluene hemisolvate
    Lee, See Mun
    Ali, Hapipah Mohd.
    Lo, Kong Mun
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O409 - U2928
  • [46] RETRACTED: Azido{1-[ 2-(dimethylamino)ethyliminomethyl]naphthalenolato}copper(II) (Retracted Article)
    Zhu, QY
    Wei, YJ
    Wang, FW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M983 - M985
  • [47] Bis{μ-2-[2-(2-pyridyl)ethyliminomethyl]phenolato}bis[azidozinc(II)]
    Zhou, Xiang-Rong
    Li, Zhong-Shu
    Zhang, Lei
    Zhou, Zhi-Hong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M791 - U560
  • [48] catena-poly[[(2-{1-[2-(2-aminoethyl-amino)ethylimino]ethyl}-5-methoxy-phenolato-κ4N,N′,N",O)copper(II)]-μ-nitrato-κ2O:O′]
    Wang, Suwen
    Li, Zhongfang
    Wang, Xutao
    Yu, Xianjin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1193 - U829
  • [49] Bis[μ-2-(1H-imidazol-2-yl)phenolato]-bis[chloromethanolcopper(II)]
    He, Hong-Shan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1782 - M1783
  • [50] {4-bromo-2-[2-(isopropylamino)ethyliminomethyl]phenolato}thiocyanatocopper(II)
    Ma, Jun-Ying
    He, Yin-Ting
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M687 - U637
12345