Synthesis of N-heterocylic carbene-containing metal complexes from 2-(pentafluorophenyl)imidazolidines

被引：69

作者：

Blum, Angela P. ^{[1
]}

Ritter, Tobias ^{[1
]}

Grubbs, Robert H. ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 08期

关键词：

D O I：

10.1021/om060949f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N-Heterocyclic carbene (NHC)-containing metal complexes are prepared through a simple, base-free method involving the decomposition of 2-(pentafluorophenyl)imidazolidines under mild thermolytic conditions. Ruthenium, iridium, and rhodium complexes containing NHC ligands with different electronic and steric parameters are reported.

引用

页码：2122 / 2124

页数：3

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