Two conformers in solution and solid state for a novel phosphoramidate -: Synthesis, characterization and crystal structures of C6H5C(O)NHP(O)[NH(tert-C4H9)]2 and CCl3C(O)NHP(O)[NH(tert-C4H9)]2

被引：32
|
作者：
Gholivand, K [1 ]
Pourayoubi, M [1 ]
机构：
[1] Tarbiat Modarres Univ, Dept Chem, Tehran, Iran
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 8-9期
关键词：
crystal structure; phosphoric triamide; NMR spectroscopy;
D O I：
10.1002/zaac.200400136
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new phosphoramidates with formula RC(O)NHP(O)[NH(tert-C4H9)](2), R=C6H5, (1) and CCl3, (2) were synthesized and characterized by IR, H-1-, C-13-, P-31 NMR, mass spectroscopy and elemental analysis. The structures confirmed by X-ray single crystal determination. Compound 1 appears as two conformers (1a and 1b) in solid state as well as solution. Both compounds (1 and 2) exist in the polymeric chains in crystalline lattice produced by hydrogen bonding that for compound 1, there are two independent infinite chains; each of them composed of one of the two conformers.
引用
收藏
页码：1330 / 1335
页数：6
相关论文
共 50 条
  • [31] Synthesis and crystal structure of a new o-ethylphenylammonium triphosphate [2-C2H5C6H4NH3]3H2P3O10
    Smirani, W
    Ben Nasr, C
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2004, 39 (7-8) : 1103 - 1111
  • [32] Synthesis and crystal structure of the binuclear complex [Pr2(C10H8N2O4)2(C10H9N2O4)2(H2O)4]•3H2O•C6H6
    Wu, WT
    Chen, FY
    He, SY
    Hu, HM
    Yang, ML
    Wang, YY
    CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (05) : 711 - 713
  • [33] Syntheses and structures of [Tb(C6NO2H5)3(H2O)2]2n(3nHgCl4)•(4nH2O) and [La(C6NO2H5)2(C6NO2H4)(H2O)2]n(nZnCl4)•(2nH2O)
    Chen, Wentong
    Hu, Long
    Lai, Chunqing
    Zhou, Wenjun
    JOURNAL OF CHEMICAL RESEARCH, 2010, (09) : 533 - 537
  • [34] SYNTHESIS AND CRYSTAL-STRUCTURE OF B10H10(C6H11)S(CH3)2CNH(TERT-C4H9)
    HERNANDEZ, DM
    HUFFMAN, JC
    TODD, LJ
    INORGANIC CHEMISTRY, 1987, 26 (01) : 213 - 215
  • [35] SYNTHESIS OF (TERT-C4H9C5H4)2SM(DME) AND ITS REACTIVITY WITH PHENYLACETYLENE - SYNTHESIS AND STRUCTURE OF ((TERT-C4H9C5H4)2SMCCPH)2
    SHEN, Q
    ZHENG, DS
    LIN, L
    LIN, YH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 391 (03) : 307 - 312
  • [36] Synthesis and crystal structure of [Tb4(H2O)2](C2O4)2(C5H6O4)4
    Thomas, P
    Trombe, JC
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (10) : 633 - 639
  • [37] Crystal growth and characterization of gadolinium tartrate trihydrate:: Gd(C4H4O6)(C4H5O6)•3H2O
    Want, Basharat
    Ahmad, Farooq
    Kotru, P. N.
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 431 (1-2): : 237 - 247
  • [38] Synthesis and crystal structure of [Tb4(H2O)2](C2O4)2(C5H6O4)4
    P. Thomas
    J.C. Trombe
    Journal of Chemical Crystallography, 2000, 30 : 633 - 639
  • [39] Synthesis of Double Uranyl Phthalates of the M-4[(UO2)(4)(mu(3)-O)(2)(C6H4C2O4)(4)] . nH(2)O Type with M = NH4, K, and Cs. Crystal Structure of K-4[(UO2)(4)O-2(C6H4C2O4)(4)] . 3H(2)O
    Charushnikova, I. A.
    Krot, N. N.
    Polyakova, I. N.
    Makarenkov, V. I.
    RADIOCHEMISTRY, 2005, 47 (03) : 241 - 246
  • [40] Crystal growth and structure of (2-C2H5C6H4NH3)2H2P2O7
    Akriche, S
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2001, 36 (1-2) : 375 - 382
12345