Catalytic alkylation of benzylic C-H bonds with 1,3-dicarbonyl compounds utilizing oxygen as terminal oxidant

被引：40

作者：

Correia, Camille A. ^{[1
]}

Li, Chao-Jun ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

DEHYDROGENATIVE-COUPLING CDC; N-HYDROXYPHTHALIMIDE; MOLECULAR-OXYGEN; OXIDATIVE CYANATION; ALLYLIC ALKYLATION; TERTIARY-AMINES; EFFICIENT; BENZYLATION; ACTIVATION; ALCOHOLS;

D O I：

10.1016/j.tetlet.2009.12.080

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative alkylation of benzylic C-H bonds with 1,3-dicarbonyl compounds was developed using oxygen as the terminal oxidant in the presence of catalytic amounts of FeCl2, CuCl and NHPL (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1172 / 1175

页数：4

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