Effect of cation capture by crown ether and polar solvent in the carboxylation with CO2 of alkali metal 2-naphtholates under ordinary conditions

被引：4
|
作者：
Baxter, J [1 ]
Yamaguchi, T [1 ]
机构：
[1] Chiba Inst Technol, Dept Ind Chem, Chiba 275, Japan
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1997年 / 10期
关键词：
D O I：
10.1039/a703432f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method for the carboxylation of sodium 2-naphtholate and potassium 2-naphtholate in benzene with 10 mol% of crown ether or aprotic polar solvents under 1 atm of carbon dioxide at 60 degrees C affords 2-hydroxynaphthalene-1-carboxylic acid in yields ranging from 14.6 to 43.8% and 26.7 to 66.0%, respectively.
引用
收藏
页码：374 / 375
页数：3
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