pH-dependent assembly of a series of inorganic-organic hybrid molybdenum(v) phosphate

被引：19
|
作者：
Zhang, Xiao [1 ,2 ,4 ,5 ]
Yi, Zhihui [3 ,4 ,5 ]
Zhao, Liyan [1 ,2 ]
Chen, Qian [1 ,2 ]
Wang, Xiaolin [1 ,2 ]
Xu, Jiqing [4 ,5 ]
Xia, Wujiong [1 ,2 ]
Yang, Chao [1 ,2 ]
机构：
[1] Harbin Inst Technol, SKLUWRE, Natl Engn Res Ctr Urban Water Resource, Harbin 150080, Heilongjiang, Peoples R China
[2] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Heilongjiang, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[4] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China
[5] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 02期
基金：
中国博士后科学基金;
关键词：
STATE COORDINATION CHEMISTRY; HYDROTHERMAL SYNTHESIS; STRUCTURAL CHARACTERIZATIONS; BUILDING-BLOCKS; PROTON-TRANSFER; CONSTRUCTION; FRAMEWORK; PHOSPHONATES; COMPLEXES; CLUSTERS;
D O I：
10.1039/b917754j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four inorganic-organic hybrid materials based on poly(oxomolybdophosphate) cluster building blocks have been obtained by hydrothermal methods. 1 shows a 2-D sheet structure, 2 and 3 possess 1-D chain structures and 4 is the discrete cluster. Crystal structural analysis reveals that the dimensionality and organization of those compounds can be tuned by the pH value of the reaction system. In addition, the fluorescence emissions are analysed of compounds 1, 2 and 4 containing Cd atoms with d(10) electronic configuration red-shift along with the increase in the dimensions of those compounds.
引用
收藏
页码：595 / 603
页数：9
相关论文
共 50 条
  • [1] Temperature-controlled assembly of a series of inorganic-organic hybrid arsenomolybdates
    Niu, Jingyang
    Hua, Jiai
    Ma, Xiang
    Wang, Jingping
    CRYSTENGCOMM, 2012, 14 (11): : 4060 - 4067
  • [2] A series of inorganic-organic hybrid composite solids based on molybdenum oxide chains
    Chen, Li-Juan
    He, Xiang
    Xia, Chang-Kun
    Zhang, Quan-Zheng
    Chen, Jiu-Tong
    Yang, Wen-Bin
    Lu, Can-Zhong
    CRYSTAL GROWTH & DESIGN, 2006, 6 (09) : 2076 - 2085
  • [3] pH-Dependent assembly of three novel inorganic-organic hybrids based on different isopolymolybdates and CuI/II(bbx)n units
    Wu, Panfeng
    Xue, Qi
    Dong, Xinbo
    Zhang, Yanjie
    Liu, Bin
    Hu, Huaiming
    Xue, Ganglin
    CRYSTENGCOMM, 2016, 18 (28): : 5320 - 5326
  • [4] pH-dependent assembly of two inorganic-organic hybrid compounds based on octamolybdates: an unusual intercalated layer and a 3D 4-connected framework
    Liu, Hai-Yan
    Yang, Jin
    Liu, Ying-Ying
    Ma, Jian-Fang
    DALTON TRANSACTIONS, 2012, 41 (33) : 9922 - 9927
  • [5] pH-Dependent Assembly of Two Novel Organic–inorganic Hybrids Based on Vanadoantimonate Clusters
    Yuanzhe Gao
    Zhangang Han
    Yanqing Xu
    Changwen Hu
    Journal of Cluster Science, 2010, 21 : 163 - 171
  • [6] A novel cobalt(II)-molybdenum(V) phosphate organic-inorganic hybrid polymer
    Shi, Fa-Nian
    Paz, Filipe A. Almeida
    Girginova, Penka I.
    Nogueira, Helena I. S.
    Rocha, Joao
    Amaral, Vitor S.
    Klinowski, Jacek
    Trindade, Tito
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (05) : 1497 - 1505
  • [7] An Organic–Inorganic Hybrid Polymer Based on Molybdenum(V) Phosphate and Cadmium(II) Complex
    Yuee Iiu
    Kai Yu
    Hui Xu
    Jinghan Wang
    Zhanhua Su
    Baibin Zhou
    Qun Wang
    Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24 : 759 - 765
  • [8] pH-Dependent Assembly of Two Novel Organic-inorganic Hybrids Based on Vanadoantimonate Clusters
    Gao, Yuanzhe
    Han, Zhangang
    Xu, Yanqing
    Hu, Changwen
    JOURNAL OF CLUSTER SCIENCE, 2010, 21 (02) : 163 - 171
  • [9] Multifunctional Phosphate-Based Inorganic-Organic Hybrid Nanoparticles
    Heck, Joachim G.
    Napp, Joanna
    Simonato, Sara
    Moellmer, Jens
    Lange, Marcus
    Reichardt, Holger M.
    Staudt, Reiner
    Alves, Frauke
    Feldmann, Claus
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (23) : 7329 - 7336
  • [10] π-π Interactions and magnetic properties in a series of hybrid inorganic-organic crystals
    Gonzalez, M.
    Lemus-Santana, A. A.
    Rodriguez-Hernandez, J.
    Knobel, M.
    Reguera, E.
    JOURNAL OF SOLID STATE CHEMISTRY, 2013, 197 : 317 - 322
12345