pH-dependent assembly of a series of inorganic-organic hybrid molybdenum(v) phosphate

被引：19
|
作者：
Zhang, Xiao [1 ,2 ,4 ,5 ]
Yi, Zhihui [3 ,4 ,5 ]
Zhao, Liyan [1 ,2 ]
Chen, Qian [1 ,2 ]
Wang, Xiaolin [1 ,2 ]
Xu, Jiqing [4 ,5 ]
Xia, Wujiong [1 ,2 ]
Yang, Chao [1 ,2 ]
机构：
[1] Harbin Inst Technol, SKLUWRE, Natl Engn Res Ctr Urban Water Resource, Harbin 150080, Heilongjiang, Peoples R China
[2] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Heilongjiang, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[4] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China
[5] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 02期
基金：
中国博士后科学基金;
关键词：
STATE COORDINATION CHEMISTRY; HYDROTHERMAL SYNTHESIS; STRUCTURAL CHARACTERIZATIONS; BUILDING-BLOCKS; PROTON-TRANSFER; CONSTRUCTION; FRAMEWORK; PHOSPHONATES; COMPLEXES; CLUSTERS;
D O I：
10.1039/b917754j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four inorganic-organic hybrid materials based on poly(oxomolybdophosphate) cluster building blocks have been obtained by hydrothermal methods. 1 shows a 2-D sheet structure, 2 and 3 possess 1-D chain structures and 4 is the discrete cluster. Crystal structural analysis reveals that the dimensionality and organization of those compounds can be tuned by the pH value of the reaction system. In addition, the fluorescence emissions are analysed of compounds 1, 2 and 4 containing Cd atoms with d(10) electronic configuration red-shift along with the increase in the dimensions of those compounds.
引用
收藏
页码：595 / 603
页数：9
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