Boosting Self-Assembly Diversity in the Solid-State by Chiral/Non-Chiral ZnII-Porphyrin Crystallization

被引：10

作者：

Qian, Wenjie ^{[1
]}

Gonzalez-Campo, Arantzazu ^{[1
]}

Perez-Rodriguez, Ana ^{[1
]}

Rodriguez-Hermida, Sabina ^{[2
,3
]}

Imaz, Inhaz ^{[2
,3
]}

Wurst, Klaus ^{[4
]}

Maspoch, Daniel ^{[2
,3
,5
]}

Ruiz, Eliseo ^{[6
,7
]}

Ocal, Carmen ^{[1
]}

Barrena, Esther ^{[1
]}

Amabilino, David B. ^{[8
]}

Aliaga-Alcalde, Nuria ^{[1
,5
]}

机构：

[1] CSIC, Inst Ciencia Mat Barcelona ICMAB, Campus Univ, Bellaterra 08193, Spain

[2] CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Campus UAB, Barcelona 08193, Spain

[3] Barcelona Inst Sci & Technol, Campus UAB, Barcelona 08193, Spain

[4] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 52a, A-6020 Innsbruck, Austria

[5] ICREA, Passeig Lluis Companys 23, Barcelona 08010, Spain

[6] Univ Barcelona, Dept Quim Inorgan & Organ, E-08007 Barcelona, Spain

[7] Univ Barcelona IQTCUB, Inst Quim Teor & Computac, Barcelona 08007, Spain

[8] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 49期

关键词：

chirality; crystal growth; self-assembly; porphyrinoids; zinc; NITRONYL NITROXIDE RADICALS; SUPRAMOLECULAR CHIRALITY; CRYSTAL-STRUCTURE; COORDINATION; INTEGRATION; SOLVENT;

D O I：

10.1002/chem.201802031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral Zn-II porphyrin derivative 1 and its achiral analogue 2 were studied in the solid state. Considering the rich molecular recognition of designed metalloporphyrins 1 and 2 and their tendency to crystallize, they were recrystallized from two solvent mixtures (CH2Cl2/CH3OH and CH2Cl2/hexane). As a result, four different crystalline arrangements (1 a,b and 2 a,b, from 0D to 2D) were obtained. Solid-state studies were performed on all the species to analyze the role played by chirality, solvent mixtures, and surfaces (mica and HOPG) in the supramolecular arrangements. By means of combinations of solvents and substrates a variety of microsized species was obtained, from vesicles to flower-shaped arrays, including geometrical microcrystals. Overall, the results emphasize the environmental susceptibility of metalloporphyrins and how this feature must be taken into account in their design.

引用

页码：12950 / 12960

页数：11

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