Incorporation effect of thin Al2O3 layers on ZrO2-Al2O3 nanolaminates in a composite oxide-high-κ-oxide stack for floating-gate flash memory devices

被引:2
|
作者
Joo, Moon Sig [1 ]
Lee, Seung Ryong [1 ]
Yang, Hong-Seon [1 ]
Hong, Kwon [1 ]
Jang, Se-Aug [1 ]
Koo, Jaehyoung [1 ]
Kim, Jaemun [1 ]
Shin, Seungwoo [1 ]
Kim, Myungok [1 ]
Pyi, Seungho [1 ]
Kwak, Nojung [1 ]
Kim, Jin Woong [1 ]
机构
[1] Hynix Semicond Inc, R&D Div, Inchon 467701, Kyoungki Do, South Korea
关键词
inter-polysilicon dielectric; ZrO2-Al2O3; nanolaminate; high-kappa; flash memory; ALD;
D O I
10.1143/JJAP.46.2193
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrate the electrical properties and reliability of ZrO2-Al2O3 nanolaminates as high-kappa dielectric materials in a composite oxide-high-kappa-oxide (OKO) stack for floating-gate flash memory devices with 40 nm technology nodes and beyond. The effects of incorporating thin Al2O3 layers into ZrO2 films as an inserting layer and a capping layer on the electrical properties and reliability are discussed. The incorporation of Al2O3 layers significantly improves the leakage current versus the capacitive-equivalent thickness (CET) and TDDB characteristics of the ZrO2-Al2O3 nanolaminate compared with those of the pure ZrO2 owing to the mismatch of the grain boundaries, improved resistance to silicon diffusion, and enhanced energetic-electron hardness of the high-K film.
引用
收藏
页码:2193 / 2196
页数:4
相关论文
共 50 条
  • [21] Ultrathin nitrided-nanolaminate (Al2O3/ZrO2/Al2O3) for metal-oxide-semiconductor gate dielectric applications
    Jeon, S
    Yang, H
    Chang, HS
    Park, DG
    Hwang, H
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2002, 20 (03): : 1143 - 1145
  • [22] Thickness dependence of Al2O3/HfO2/Al2O3 stacked tunneling layers on gadolinium oxide nanocrystal nonvolatile memory
    Wang, Jer-Chyi
    Chen, Chia-Hsin
    Lin, Chih-Ting
    MICROELECTRONIC ENGINEERING, 2015, 138 : 52 - 56
  • [23] Indentation testing of an Al2O3/Al2O3+ZrO2 layered composite
    Zimovcák, P
    Köves, T
    Dusza, J
    Pesek, L
    Chalvet, F
    De Portu, G
    FRACTOGRAPHY OF ADVANCED CERAMICS II, 2005, 290 : 316 - 319
  • [24] Conditions for Preparation of Oxide Components and Their Effect on Properties of Al2O3 – ZrO2 – SiC Composite
    Yu. I. Ryabkov
    P. A. Sitnikov
    Refractories and Industrial Ceramics, 2003, 44 : 115 - 118
  • [25] The effect of fixed oxide charge in Al2O3 blocking dielectric on memory properties of charge trap flash memory devices
    Jeon, S
    Kim, C
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (08) : G265 - G267
  • [26] Lu2O3/Al2O3 gate dielectrics for germanium metal-oxide-semiconductor devices
    Darmawan, P.
    Chan, M. Y.
    Zhang, T.
    Setiawan, Y.
    Seng, H. L.
    Chan, T. K.
    Osipowicz, T.
    Lee, P. S.
    APPLIED PHYSICS LETTERS, 2008, 93 (06)
  • [27] DISTRIBUTION OF ZRO2 AND AL2O3 IN ULTRAFINE ZRO2-AL2O3 POWDERS FORMED BY THE SPRAY-ICP TECHNIQUE
    KAGAWA, M
    IMAMURA, Y
    USUI, S
    SYONO, Y
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1984, 3 (08) : 699 - 702
  • [28] Nanostructured composite ceramic materials in the ZrO2-Al2O3 system
    Khrustov, V. R.
    Ivanov, V. V.
    Kotov, Yu. A.
    Kaigorodov, A. S.
    Ivanova, O. F.
    GLASS PHYSICS AND CHEMISTRY, 2007, 33 (04) : 379 - 386
  • [29] Nanostructured composite ceramic materials in the ZrO2-Al2O3 system
    V. R. Khrustov
    V. V. Ivanov
    Yu. A. Kotov
    A. S. Kaigorodov
    O. F. Ivanova
    Glass Physics and Chemistry, 2007, 33 : 379 - 386
  • [30] Tetragonal ZrO2/Al2O3 Stack as High-κ Gate Dielectric for Si-Based MOS Devices
    Wu, Yung-Hsien
    Chen, Lun-Lun
    Lyu, Rong-Jhe
    Li, Ming-Yen
    Wu, Hsiao-Che
    IEEE ELECTRON DEVICE LETTERS, 2010, 31 (09) : 1014 - 1016