Specific features of polyamidine interaction with low-molecular-mass bisphenols

被引:0
|
作者
Nikolaeva, MN [1 ]
Vlasova, EN [1 ]
Dudkina, MM [1 ]
Ten'kovtsev, AV [1 ]
机构
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The process of hydrogen bond formation upon the interaction of poly(1, 10-decamethyleneacetamidine) with bisphenols was investigated. Using the proton NMR method, it was shown that the formation of intermolecular hydrogen bonds between poly(1, 10-decamethyleneacetamidine) and bisphenols results from the competing processes of degradation of the network of interchain hydrogen bonds in the polymer and formation of new bonds due to noncovalent interactions of the polymer with a low-molecular-mass compound.
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页码:1228 / 1231
页数:4
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