Synthesis of magnetic oxidized multiwalled carbon nanotube-κ-carrageenan-Fe3O4 nanocomposite adsorbent and its application in cationic Methylene Blue dye adsorption

In this study, magnetic oxidized multiwalled carbon nanotube (OMWCNT)-Fe3O4 and OMWCNT-kappa-carrageenan-Fe3O4 nanocomposites were synthesized and used as adsorbent for the removal of Methylene Blue (MB) from aqueous solution. Magnetic nanocomposites were characterized by using of specific surface area, Fourier transform infrared, X-ray diffraction, vibrating sample magnetometry, thermal gravimetric analysis, scanning electron microscope and transmission electron microscope measurements. The results of characterization analyses exhibited that OMWCNT was successfully modified with kappa-carrageenan. Furthermore, OMWCNT-Fe3O4 and OMWCNT-kappa-carrageenan-Fe3O4 nanocomposites were of a super-paramagnetic property. Adsorption studies revealed that the data of adsorption kinetics and isotherm were well fitted by the pseudo second-order kinetic model and Langmuir isotherm model, respectively. The adsorption amounts of magnetic adsorbents increased with contact time and initial dye concentration. Compared with magnetic OMWCNT-Fe3O4 nanocomposite, magnetic OMWCNT-kappa-carrageenan-Fe3O4 nanocomposite showed a better adsorption performance for the removal of MB from aqueous solution. Therefore, OMWCNT-kappa-carrageenan-Fe3O4 nanocomposite may be used as a magnetic adsorbent to remove the cationic dyes from wastewaters. (C) 2016 Elsevier Ltd. All rights reserved.