Origin of the effect of ion nature on the differential capacity of an interface between two immiscible electrolyte solutions

被引:18
|
作者
Samec, Z [1 ]
Trojanek, A [1 ]
Langmaier, J [1 ]
机构
[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem & Electrochem, CR-18223 Prague 8, Czech Republic
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 444卷 / 01期
关键词
immiscible electrolyte solutions; capacity; capillary waves;
D O I
10.1016/S0022-0728(97)00590-1
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
It is shown that the experimentally observed effect of ion nature on the capacity of the interface between two immiscible electrolyte solutions can be linked to periodic mechano-electric perturbations of the interfacial region during the ac impedance measurements rather than to the specific ion adsorption. (C) 1998 Elsevier Science S.A. All rights reserved.
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页码:1 / 5
页数:5
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