Line shapes of multiple quantum NMR coherences in one-dimensional quantum spin chains in solids

被引：15
|
作者：
Doronin, SI [1 ]
Fel'dman, EB [1 ]
Maximov, II [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
JOURNAL OF MAGNETIC RESONANCE | 2004年 / 171卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
MQ NMR; MQ spin dynamics; MQ correlators;
D O I：
10.1016/j.jmr.2004.07.017
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
General formulae for intensities of multiple quantum (MQ) NMR coherences in systems of nuclear spins coupled by the dipole-dipole interactions are derived. The second moments of the MQ coherences of zero- and second orders are calculated for infinite linear chains in the approximation of the nearest neighbor interactions. Supercomputer simulations of intensities of MQ coherences of linear chains are performed at different times of preparation and evolution periods of MQ NMR experiments. The second moments obtained from the developed theory are compared with the results of the supercomputer analysis of MQ MMR dynamics. The linewidth information in MQ MMR experiments is discussed. (C) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码：37 / 42
页数：6
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