A Study of Complex Formation Between Polyacrylic Acid and Poly(Ethylene Oxide) by Near Resonance Rayleigh Scattering

被引：6
|
作者：
Li, Yunbo [1 ]
Li, Haixia [1 ,2 ]
Sun, Yantao [1 ]
Chen, Xudong [2 ]
Zhu, Yubin [1 ]
机构：
[1] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200072, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
来源：
APPLIED SPECTROSCOPY | 2010年 / 64卷 / 06期
关键词：
Complexation; Resonance Rayleigh scattering; RRS; Near resonance Rayleigh scattering; NRRS; Polyacrylic acid; Poly(ethylene oxide); Phase segregation; LIGHT-SCATTERING; POLY(ACRYLIC ACID); GOLD NANOPARTICLES; NONLINEAR SCATTERING; SERUM; PH; FLUORESCENCE; RESOLUTION; PORPHYRIN; GLYCOL);
D O I：
10.1366/000370210791414371
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
A series of near resonance Rayleigh scattering (NRRS) experiments has been performed on the phase behavior of complex formation between polyacrylic acid (PAA) and poly(ethylene oxide) (POE). On the basis of the theory of resonance scattering, as one new method compared to resonance Rayleigh scattering (RRS), NRRS was demonstrated to investigate polymer solutions. The results indicated that the complex formation induces an increase of the intensity of resonance scattering and the phase segregation leads to distortion of the resonance scattering spectrum with decreasing pH value. The collapse of macromolecular chains is attributed to the contraction of PAA chains and association between PAA and POE. Moreover, NRRS can show more information than RRS on the basis of their scattering spectra.
引用
收藏
页码：682 / 686
页数：5
相关论文
共 50 条
  • [21] THERMAL-EQUILIBRIUM IN PROCESS OF COMPLEX-FORMATION BETWEEN POLY(METHACRYLIC ACID) AND POLY(ETHYLENE GLYCOL)
    OSADA, Y
    SATO, M
    NIPPON KAGAKU KAISHI, 1976, (01) : 175 - 179
  • [22] Complex formation between poly(vinyl ether) of ethylene glycol and poly(acrylic acid) in aqueous and organic solutions
    Mun, GA
    Nurkeeva, ZS
    Khutoryanskiy, VV
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (09) : 2136 - 2138
  • [23] Complex micelle formation between poly(ethylene oxide-b-N-methyl-2-vinylpyridinium iodide) and poly(methacrylic acid) in aqueous solutions
    Guragain, Sudhina
    Bastakoti, Bishnu P.
    Hasegawa, Masatoshi
    Nakashima, Kenichi
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2010, 363 (1-3) : 86 - 91
  • [24] Study on the Interaction Between Oxymatrine and Tungstosilicic Acid by Resonance Rayleigh Scattering and Its Analytical Applications
    Li, Junbo
    Yang, Xiaoli
    Yang, Jinxiang
    He, Yanbin
    SPECTROSCOPY LETTERS, 2015, 48 (02) : 153 - 158
  • [25] FORMATION AND CHARACTERIZATION OF AN INSOLUBLE POLY-ELECTROLYTE COMPLEX - CHITOSAN-POLYACRYLIC ACID
    CHAVASIT, V
    KIENZLESTERZER, C
    TORRES, JA
    POLYMER BULLETIN, 1988, 19 (03) : 223 - 230
  • [26] The isomer effect on complex formation in poly(ethylene oxide)nitrophenol system
    Tsutsui, K
    Adachi, K
    Tsujita, Y
    Yoshimizu, H
    Kinoshita, T
    POLYMER JOURNAL, 1998, 30 (09) : 753 - 757
  • [27] The Isomer Effect on Complex Formation in Poly(ethylene oxide)-Nitrophenol System
    Kimiaki Tsutsui
    Kanato Adachi
    Yoshiharu Tsujita
    Hiroaki Yoshimizu
    Takatoshi Kinoshita
    Polymer Journal, 1998, 30 : 753 - 757
  • [28] FLUORESCENCE POLARIZATION STUDY OF THE POLY(ACRYLIC ACID) POLY(ETHYLENE OXIDE) INTERPOLYMER COMPLEX IN AQUEOUS-SOLUTION
    HEYWARD, JJ
    GHIGGINO, KP
    MACROMOLECULES, 1989, 22 (03) : 1159 - 1165
  • [29] STRUCTURAL STUDY ON THE MICELLE FORMATION OF POLY(ETHYLENE OXIDE) POLY(PROPYLENE OXIDE) POLY(ETHYLENE OXIDE) TRIBLOCK COPOLYMER IN AQUEOUS-SOLUTION
    MORTENSEN, K
    PEDERSEN, JS
    MACROMOLECULES, 1993, 26 (04) : 805 - 812
  • [30] INTERLAMELLAR COMPLEX-FORMATION BETWEEN VARIOUS ION FORMS OF MONTMORILLONITE AND POLY(ETHYLENE OXIDE) OF POLYACRYLAMIDE
    TANIHARA, K
    NAKAGAWA, M
    NIPPON KAGAKU KAISHI, 1975, (05) : 782 - 789
12345