Synthesis, Structure and Properties of Donor-acceptor-type [4]Dendralenes

被引：0
|
作者：
Matsumoto, Yuya [1 ]
Matsuda, Rina [1 ]
Yoshimura, Aya [1 ,2 ]
Shirahata, Akashi [1 ,2 ,3 ]
Misaki, Yohji [1 ,2 ,3 ]
机构：
[1] Ehime Univ, Grad Sch Sci & Engn, Dept Appl Chem, 3 Bunkyo cho, Matsuyama, Ehime 7908577, Japan
[2] Ehime Univ, Res Unit Power Generat & Storage Mat, Matsuyama, Ehime 7908577, Japan
[3] Ehime Univ, Res Unit Dev Organ Superconductors, Matsuyama, Ehime 7908577, Japan
来源：
CHEMISTRY LETTERS | 2022年 / 51卷 / 05期
关键词：
Dendralene; X-ray structure analysis; Cyclic voltammetry; X-RAY; TETRACYANOETHYLENE TCNE; TETRATHIAFULVALENE TTF; OPTICAL-PROPERTIES; CHARGE-TRANSFER; 1,3-DITHIOL-2-YLIDENE; ELECTROCHEMISTRY; REFINEMENT; ANALOGS; SYSTEMS;
D O I：
10.1246/cl.220064
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[4]Dendralene and its analogs possessing both strongly electron-donating 1,3-dithiol-2-ylidenes and electron-accepting dicyanomethylidenes (2b-4b) were successfully synthesized. X-ray structure analysis revealed that 2b adopts a nonplanar structure, in which half units of 2b are significantly inclined to each other. Cyclic voltammograms of 2b-4b consisted of one pair of two-electron oxidation waves and one pair of one-electron reduction waves.
引用
收藏
页码：581 / 584
页数：4
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