Palladium nanoparticles as efficient green homogeneous and heterogeneous carbon-carbon coupling precatalysts: A unifying view

被引:741
|
作者
Astruc, Didier [1 ]
机构
[1] Univ Bordeaux 1, Mol Nanosci & Catakysis Grp, LCOO, UMR 5802,CNRS, F-33405 Talence, France
关键词
LIGAND-FREE PALLADIUM; CATALYZED HECK REACTION; DENDRIMER-ENCAPSULATED PD; POLYMER-INCARCERATED PALLADIUM; SUZUKI-MIYAURA REACTION; ARYL CHLORIDES; COPPER-FREE; METAL NANOPARTICLES; RECYCLABLE CATALYST; IONIC LIQUIDS;
D O I
10.1021/ic062183h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Pd catalysis of C-C bond formations is briefly reviewed from the angle of nanoparticles (NPs) whether they are homogeneous or heterogeneous precatalysts and whether they are intentionally preformed or generated from a Pd derivative such as Pd(OAc)(2). The most studied reaction is the Heck coupling of halogenoarenes with olefins that usually proceeds at high temperature (120-160 degrees C). Under such conditions, the Pd-II precursor is reduced to Pd-0, forming PdNPs from which Pd atom leaching, subsequent to oxidative addition of the aryl halide onto the PdNP surface, is the source of very active molecular catalysts. Other C-C coupling reactions (Suzuki, Sonogashira, Stille, Negishi, Hiyama, Corriu-Kumada, Ullmann, and Tsuji-Trost) can also be catalyzed by species produced from preformed PdNPs. For catalysis of these reactions, leaching of active Pd atoms from the PdNPs may also provide a viable molecular mechanistic scheme. Thus, the term "PdNP catalysis of C-C coupling" used in this review refers to this function of PdNPs as precursors of catalytically active Pd species (i.e., the PdNPs are precatalysts of C-C coupling reactions).
引用
收藏
页码:1884 / 1894
页数:11
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