A lithium anode protection guided highly-stable lithium-sulfur battery

被引：356
|
作者：
Ma, Guoqiang [1 ]
Wen, Zhaoyin [1 ]
Wu, Meifen [1 ]
Shen, Chen [1 ]
Wang, Qingsong [1 ]
Jin, Jun [1 ]
Wu, Xiangwei [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 91期
关键词：
HIGH-PRESSURE; CATHODE; COMPOSITE; LI3N; PERFORMANCE; GRAPHENE; LI/S;
D O I：
10.1039/c4cc05535g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Li3N protection layer is fabricated on the surface of a Li anode by an in situ method to suppress the shuttle effect on the basis of anode protection. The discharge capacity is retained at 773 mA h g(-1) after 500 cycles with an average coulombic efficiency of 92.3% in the electrolyte without LiNO3, while the sulfur loading of the simple sulfur cathode was 2.5-3 mg cm(-2).
引用
收藏
页码：14209 / 14212
页数：4
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