Diisopropoxyaluminium trifluoroacetate/4-nitrobenzaldehyde - A new Oppenauer oxidation system for accelerated oxidation of secondary alcohols to the corresponding ketones

被引：19
|
作者：
Akamanchi, KG
Chaudhari, BA
机构：
[1] Pharmaceut. and Fine Chem. Division, Department of Chemical Technology, University of Mumbai, Matunga
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 39期
关键词：
D O I：
10.1016/S0040-4039(97)01623-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical, efficient and accelerated oxidation of secondary alcohols to the corresponding ketones has been achieved at rt in high yields by a modified Oppenauer oxidation system using diisopropoxyaluminium trifluoroacetate as catalyst and 4-nitrobenzaldehyde as a hydride acceptor. (C) 1997 Elsevier Science Ltd.
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页码：6925 / 6928
页数：4
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