The Mn(acac)3-RCN-CCl4 system as a new efficient reagent for the oxidation of secondary alcohols into ketones

被引：6
|
作者：
Khusnutdinov, RI
Schadneva, NA
Baiguzina, AR
Dzhemilev, UM
机构：
[1] Acad Sci Bashkortostan Republ, Inst Petr Chem & Catalysis, Ufa 450075, Russia
[2] Russian Acad Sci, Ufa Res Ctr, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
secondary alcohols; catalysis; manganese complexes; nitriles; oxidation; ketones;
D O I：
10.1023/A:1019638407972
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Mn(acac)(3)-RCN-CCl4 system was found to be efficient for the oxidation of secondary alcohols into the corresponding ketones in 80-93% yields. The oxidation proceeds through the formation of alkyl hypochlorites, which are generated from CCl4 and the alcohols in the presence of the Mn(acac)(3)-RCN catalytic system (R = Me, Et, and Ph).
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页码：1065 / 1067
页数：3
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