Palladium-catalyzed C-H olefination of uracils and caffeines using molecular oxygen as the sole oxidant

被引：14
|
作者：
Zhang, Xinyu [1 ,2 ]
Su, Lv [1 ,2 ]
Qiu, Lin [1 ,2 ]
Fan, Zhenwei [1 ,2 ]
Zhang, Xiaofeng [1 ,2 ]
Lin, Shen [1 ,2 ]
Huang, Qiufeng [1 ,2 ]
机构：
[1] Fujian Normal Univ, Coll Chem & Chem Engn, Fuzhou 350007, Peoples R China
[2] Fujian Key Lab Polymer Mat, Fuzhou 350007, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 16期
基金：
中国国家自然科学基金;
关键词：
DEHYDROGENATIVE HECK REACTIONS; FLUORESCENT CORE FRAMEWORKS; AMINO-ACID LIGANDS; BOND ACTIVATION; MECHANISTIC FEATURES; ATMOSPHERIC DIOXYGEN; OPTICAL-PROPERTIES; DIRECTING GROUPS; ALKENYLATION; FUNCTIONALIZATION;
D O I：
10.1039/c7ob00616k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium-catalyzed oxidative C-H olefination of uracils or caffeines with alkenes using an atmospheric pressure of molecular oxygen as the sole oxidant has been disclosed. This novel strategy offers an efficient and environmentally friendly method to biologically important C5-alkene uracil derivatives or C8-alkene caffeine derivatives.
引用
收藏
页码：3499 / 3506
页数：8
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