Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

被引：22

作者：

Kawakami, Ryosuke ^{[1
,2
]}

Kuriyama, Shogo ^{[1
,2
]}

Tanaka, Hiromasa ^{[3
]}

Arashiba, Kazuya ^{[1
,2
]}

Konomi, Asuka ^{[4
]}

Nakajima, Kazunari ^{[5
]}

Yoshizawa, Kazunari ^{[4
]}

Nishibayashi, Yoshiaki ^{[1
,2
]}

机构：

[1] Univ Tokyo, Dept Syst Innovat, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[2] Univ Tokyo, Sch Engn, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[3] Daido Univ, Sch Liberal Arts & Sci, Minami Ku, Nagoya, Aichi 4578530, Japan

[4] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka, Fukuoka 8190395, Japan

[5] Univ Tokyo, Sch Engn, Frontier Res Ctr Energy & Resources, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 99期

关键词：

N-2-TO-NH3; CONVERSION; MOLECULAR DINITROGEN; SILYLATION; MOLYBDENUM; NITROGEN; AMMONIA; N-2; SILYLAMINE; REACTIVITY; TURNOVER;

D O I：

10.1039/c9cc06896a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction undermild reaction conditions.

引用

页码：14886 / 14889

页数：4

共 48 条

[21] Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand
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