Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

被引：22

作者：

Kawakami, Ryosuke ^{[1
,2
]}

Kuriyama, Shogo ^{[1
,2
]}

Tanaka, Hiromasa ^{[3
]}

Arashiba, Kazuya ^{[1
,2
]}

Konomi, Asuka ^{[4
]}

Nakajima, Kazunari ^{[5
]}

Yoshizawa, Kazunari ^{[4
]}

Nishibayashi, Yoshiaki ^{[1
,2
]}

机构：

[1] Univ Tokyo, Dept Syst Innovat, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[2] Univ Tokyo, Sch Engn, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[3] Daido Univ, Sch Liberal Arts & Sci, Minami Ku, Nagoya, Aichi 4578530, Japan

[4] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka, Fukuoka 8190395, Japan

[5] Univ Tokyo, Sch Engn, Frontier Res Ctr Energy & Resources, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 99期

关键词：

N-2-TO-NH3; CONVERSION; MOLECULAR DINITROGEN; SILYLATION; MOLYBDENUM; NITROGEN; AMMONIA; N-2; SILYLAMINE; REACTIVITY; TURNOVER;

D O I：

10.1039/c9cc06896a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction undermild reaction conditions.

引用

页码：14886 / 14889

页数：4

共 48 条

[1] Preparation and reactivity of molybdenum complexes bearing pyrrole-based PNP-type pincer ligand
Tanabe, Yoshiaki
Sekiguchi, Yoshiya
Tanaka, Hiromasa
Konomi, Asuka
Yoshizawa, Kazunari
Kuriyama, Shogo
Nishibayashi, Yoshiaki
CHEMICAL COMMUNICATIONS, 2020, 56 (51) : 6933 - 6936
[2] Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands
Sekiguchi, Yoshiya
Meng, Fanqiang
Tanaka, Hiromasa
Eizawa, Aya
Arashiba, Kazuya
Nakajima, Kazunari
Yoshizawa, Kazunari
Nishibayashi, Yoshiaki
DALTON TRANSACTIONS, 2018, 47 (33) : 11322 - 11326
[3] Iron pyrrole-based PNP pincer ligand complexes as catalyst precursors
Holland, Amanda M.
Oliver, Allen G.
Iluc, Vlad M.
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2017, 73 : 569 - 574
[4] A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia
Arashiba K.
Miyake Y.
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Nature Chemistry, 2011, 3 (2) : 120 - 125
[5] Synthesis and reactivity of iron-dinitrogen complexes bearing anionic methyl- and phenyl-substituted pyrrole-based PNP-type pincer ligands toward catalytic nitrogen fixation
Sekiguchi, Yoshiya
Kuriyama, Shogo
Eizawa, Aya
Arashiba, Kazuya
Nakajima, Kazunari
Nishibayashi, Yoshiaki
CHEMICAL COMMUNICATIONS, 2017, 53 (88) : 12040 - 12043
[6] A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia
Arashiba, Kazuya
Miyake, Yoshihiro
Nishibayashi, Yoshiaki
NATURE CHEMISTRY, 2011, 3 (02) : 120 - 125
[7] Pyrrole-Based New Diphosphines: Pd and Ni Complexes Bearing the PNP Pincer Ligand
Kumar, Shanish
Mani, Ganesan
Mondal, Sukanta
Chattaraj, Pratim Kumar
INORGANIC CHEMISTRY, 2012, 51 (22) : 12527 - 12539
[8] Synthesis and Catalytic Activity of Molybdenum-Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
Kinoshita, Eriko
Arashiba, Kazuya
Kuriyama, Shogo
Miyake, Yoshihiro
Shimazaki, Ryuji
Nakanishi, Haruyuki
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ORGANOMETALLICS, 2012, 31 (23) : 8437 - 8443
[9] Gold(I) complexes bearing a PNP-type pincer ligand: photophysical properties and catalytic investigations
Casciotti, Martina
Romo-Islas, Guillermo
Alvarez, Maria
Molina, Francisco
Munoz-Molina, Jose Maria
Belderrain, Tomas R.
Rodriguez, Laura
DALTON TRANSACTIONS, 2022, 51 (45) : 17162 - 17169
[10] Synthesis and characterization of pyrrole-based group 4 PNP pincer complexes
Gerald Tomsu
Berthold Stöger
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Monatshefte für Chemie - Chemical Monthly, 2024, 155 : 173 - 181

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