Sensitized photo-oxidation of osazone by uranyl ions

被引：0
|
作者：
Vaidya, R [1 ]
Gangotri, KM [1 ]
机构：
[1] JNV Univ, Dept Chem, Jodhpur 342001, Rajasthan, India
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2004年 / 81卷 / 08期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Glucosazone quenches excited uranyl ions, which involves excited state charge transfer complex (exciplex) formation. The quenching behaviour shows pH dependence. At pH 2.00, glucosone has been characterized as the photoproduct and intermediacy of uranium(v) is proved spectrophotmetrically. A mechanism has been proposed.
引用
收藏
页码：707 / 708
页数：2
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