Separation of biobutanol from ABE fermentation broth using lignin as adsorbent: A totally sustainable approach with effective utilization of lignocellulose

被引：10

作者：

Li, Hao ^{[1
]}

Wang, Haoyang ^{[1
]}

Darwesh, Osama M. ^{[2
]}

Du, Jingjing ^{[1
]}

Liu, Shan ^{[1
]}

Li, Chunli ^{[1
]}

Fang, Jing ^{[1
]}

机构：

[1] Hebei Univ Technol, Sch Chem Engn & Technol, Natl Local Joint Engn Lab Energy Conservat Chem P, Tianjin, Peoples R China

[2] Natl Res Ctr, Agr Microbiol Dept, Agr & Biol Res Div, Cairo, Egypt

来源：

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES | 2021年 / 174卷

基金：

中国国家自然科学基金;

关键词：

Lignin; Adsorption; Biobutanol;

D O I：

10.1016/j.ijbiomac.2021.01.095

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Adsorption is considered to be a promising butanol recovery method for solving the issue of inhibition in the ABE (acetone-butanol-ethanol) fermentation. As a byproduct in the second generation biobutanol industry, lignin was found to be a good adsorbent for the butanol enrichment. It is conducive to the full utilization of renewable lignocellulose biomass resource. Kinetic and equilibrium experiments indicated that lignin had a satisfactory adsorption rate and capacity that are comparable to those of many synthetic materials. Multicomponent adsorption experiments revealed that lignin had higher adsorption selectivity toward butanol than that of ethanol and acetone. The adsorption capacity of lignin for butanol first increased and then gradually decreased with increasing temperature. And maximum adsorption capacity reached 304.66 mg g(-1) at 313 K. The inflection point of temperature is dose to the ABE fermentation temperature of 310 K. The condensed butanol by desorption was 145 g L-1, with a satisfying regeneration performance. H-1 NMR and FT-IR spectra indicated that the aromatic units of lignin formed pi-systems with A/B/E. The pi-system is particularly significant for butanol due to its longer hydrocarbon chain. These results could contribute to the emerging lignin-based materials for butanol separation. (C) 2021 Published by Elsevier B.V.

引用

页码：11 / 21

页数：11