Molecular Orientation Dependence of the Ionization Energy of Pentacene in Thin Films

被引：4

作者：

Heimel, Georg ^{[1
]}

Koch, Norbert ^{[1
]}

机构：

[1] Humboldt Univ, Inst Phys, D-12489 Berlin, Germany

来源：

INTERFACE CONTROLLED ORGANIC THIN FILMS | 2009年 / 129卷

关键词：

AUGMENTED-WAVE METHOD; WORK FUNCTION; METALS;

D O I：

10.1007/978-3-540-95930-4_23

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

An isolated individual molecule clearly has only one ionization energy. For ordered molecular assemblies, however, multiple values have been found depending on the orientation of the molecules relative to a supporting substrate. This intriguing observation is rationalized here for the prototypical molecule pentacene, in terms of intrinsic "surface dipoles" built into the molecules, which collectively give rise to the orientation dependence of the molecular ionization energy.

引用

页码：141 / 145

页数：5

共 50 条

[31] Molecular orientation within thin films of isomorphic molecular semiconductors
Liu, Xiaofeng
Burgers, Mark A.
Hsu, Ben B. Y.
Coughlin, Jessica E.
Perez, Louis A.
Heeger, Alan J.
Bazan, Guillermo C.
RSC ADVANCES, 2015, 5 (108): : 89144 - 89148
[32] Ionization potentials of crystalline organic thin films: Position dependence due to molecular shape and charge redistribution
Topham, Benjamin J.
Kumar, Manoranjan
Soos, Zoltan G.
CHEMICAL PHYSICS LETTERS, 2010, 493 (4-6) : 251 - 254
[33] Photochemical stabilization of pentacene and a substituted pentacene in solution and in thin films
Maliakal, AJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U40 - U40
[34] Orientation dependence of the electrocaloric effect of ferroelectric bilayer thin films
Qiu, J. H.
Jiang, Q.
SOLID STATE COMMUNICATIONS, 2009, 149 (37-38) : 1549 - 1552
[35] Substrate orientation dependence of the growth of GaSe thin films on GaAs
Tatsuyama, C
Nishiwaki, H
Asai, K
Lim, KK
Tambo, T
Ueba, H
APPLIED SURFACE SCIENCE, 1997, 117 : 523 - 529
[36] Orientation dependence of resistive hysteresis in bismuth ferrite thin films
Department of Materials Science, Sichuan University, 610064, China
Wu, J. (wujiagang0208@163.com), 1600, Elsevier Ltd (569):
[37] Orientation dependence of resistive hysteresis in bismuth ferrite thin films
Wu, Jiagang
Wang, Xiaopeng
Zhang, Binyu
Zhu, Jianguo
Xiao, Dingquan
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 569 : 126 - 129
[38] Photochemical stability of pentacene and a substituted pentacene in solution and in thin films
Maliakal, A
Raghavachari, K
Katz, H
Chandross, E
Siegrist, T
CHEMISTRY OF MATERIALS, 2004, 16 (24) : 4980 - 4986
[39] Growth dynamics of pentacene thin films
Frank-J. Meyer zu Heringdorf
M. C. Reuter
R. M. Tromp
Nature, 2001, 412 : 517 - 520
[40] Growth of pentacene thin films.
Tromp, RM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U637 - U637

← 1 2 3 4 5 →