Water-promoted highly selective anti-Markovnikov addition of thiols to unactivated alkenes

被引:65
|
作者
Ranu, Brindaban C. [1 ]
Mandal, Tanmay [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India
关键词
water; anti-Markovnikov addition; thiol; thioether; unactivated alkene;
D O I
10.1055/s-2007-973877
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The highly selective anti-Markovnikov addition of thiols to unactivated alkenes is demonstrated in water at room temperature without any additive. This is a very simple and efficient method for the synthesis of linear thioethers.
引用
收藏
页码:925 / 928
页数:4
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