Appel Reaction of Carboxylic Acids with Tribromoisocyanuric Acid/Triphenylphosphine: a Mild and Acid-Free Preparation of Esters and Amides

被引：9

作者：

Sindra, Haryadylla da Cunha ^{[1
]}

de Mattos, Marcio C. S. ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Dept Quim Organ, Inst Quim, CP 68545, BR-21945970 Rio De Janeiro, RJ, Brazil

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2016年 / 27卷 / 06期

关键词：

amides; esters; tribromoisocyanuric acid; acylation; triphenylphosphine; TRICHLOROISOCYANURIC ACID; REGIOSELECTIVE COIODINATION; TRIIODOISOCYANURIC ACID; FREE ESTERIFICATION; ALCOHOLS; REAGENT; TRIPHENYLPHOSPHINE; CONVERSION; CHLORIDES; BROMIDES;

D O I：

10.5935/0103-5053.20160006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and efficient method for esterification and amidation of carboxylic acids under neutral conditions has been developed. Esters and amides can be prepared by reacting a carboxylic acid (1 mmol) with tribromoisocyanuric acid (0.37 mmol) and triphenylphosphine (1 mmol) in dichloromethane at room temperature, followed by addition of an alcohol or an amine, respectively.

引用

页码：1129 / 1136

页数：8

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