Thermal Properties of Alkali Bis(pentafluoroethylsulfonyl)amides and Their Binary Mixtures

被引：18

作者：

Kubota, Keigo ^{[1
]}

Nohira, Toshiyuki ^{[1
]}

Hagiwara, Rika ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 07期

关键词：

ELECTROLYTES; SALTS;

D O I：

10.1021/je900902z

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal properties of alkali bis(pentafluoroethylsulfonyl)amides, MPf(2)N (M = Li, Na, K, Rb, and Cs), and their binary mixtures have been revealed. Phase diagrams have been constructed for 10 binary systems, and their eutectic compositions and temperatures have been determined. It was found that the molten salt electrolytes with melting points in the intermediate temperature range (450 to 650) K are easily formed by mixing two kinds of single MPf(2)N salts.

引用

页码：2546 / 2549

页数：4

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