Thermal Properties of Alkali Bis(pentafluoroethylsulfonyl)amides and Their Binary Mixtures

被引：18
|
作者：
Kubota, Keigo [1 ]
Nohira, Toshiyuki [1 ]
Hagiwara, Rika [1 ]
机构：
[1] Kyoto Univ, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 07期
关键词：
ELECTROLYTES; SALTS;
D O I：
10.1021/je900902z
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Thermal properties of alkali bis(pentafluoroethylsulfonyl)amides, MPf(2)N (M = Li, Na, K, Rb, and Cs), and their binary mixtures have been revealed. Phase diagrams have been constructed for 10 binary systems, and their eutectic compositions and temperatures have been determined. It was found that the molten salt electrolytes with melting points in the intermediate temperature range (450 to 650) K are easily formed by mixing two kinds of single MPf(2)N salts.
引用
收藏
页码：2546 / 2549
页数：4
相关论文
共 50 条
  • [1] Thermal Properties of Alkali Bis(fluorosulfonyl)amides and Their Binary Mixtures
    Kubota, Keigo
    Nohira, Toshiyuki
    Hagiwara, Rika
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09): : 3142 - 3146
  • [2] Electrochemical properties of alkali bis(trifluoromethylsulfonyl)amides and their eutectic mixtures
    Kubota, Keigo
    Tamaki, Kenichiro
    Nohira, Toshiyuki
    Goto, Takuya
    Hagiwara, Rika
    ELECTROCHIMICA ACTA, 2010, 55 (03) : 1113 - 1119
  • [3] Thermal properties of mixed alkali bis(trifluoromethylsulfonyl)amides
    Hagiwara, Rika
    Tamaki, Kenichiro
    Kubota, Keigo
    Goto, Takuya
    Nohira, Toshiyuki
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (02): : 355 - 358
  • [4] Thermal Properties of Alkali (Fluorosulfonyl)(trifluoromethylsulfonyl)amides
    Kubota, Keigo
    Nohira, Toshiyuki
    Hagiwara, Rika
    Matsumoto, Hajime
    CHEMISTRY LETTERS, 2010, 39 (12) : 1303 - 1304
  • [5] Novel inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Binary mixtures of alkali bis(fluorosulfonyl)amides
    Kubota, Keigo
    Nohira, Toshiyuki
    Goto, Takuya
    Hagiwara, Rika
    ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (12) : 1886 - 1888
  • [6] THERMAL DIFFUSION IN MOLTEN BINARY MIXTURES OF SILVER NITRATE WITH ALKALI NITRATES
    BACKLUND, V
    DUPUY, J
    GUSTAFSS.S
    LUNDEN, A
    ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1967, A 22 (04): : 471 - &
  • [7] Thermal properties of binary mixtures of β-cyclodextrin with carbamazepine polymorphs
    Cvetkovskii, A
    Bettini, R
    Tasic, L
    Stupar, M
    Casini, I
    Rossi, A
    Giordano, F
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 68 (02) : 669 - 678
  • [8] Thermal Properties of Binary Mixtures of β-Cyclodextrin with Carbamazepine Polymorphs
    A. Cvetkovskii
    R. Bettini
    Lj. Tasic
    M. Stupar
    I. Casini
    A. Rossi
    F. Giordano
    Journal of Thermal Analysis and Calorimetry, 2002, 68 : 669 - 678
  • [9] Ternary phase diagrams of alkali bis(trifluoromethylsulfonyl)amides
    Kubota, Keigo
    Nohira, Toshiyuki
    Goto, Takuya
    Hagiwara, Rika
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (09): : 2144 - 2147
  • [10] Dielectric properties and hydrogen bonding interaction behaviour in binary mixtures of glycerol with amides and amines
    Sengwa, R. J.
    Khatri, Vinita
    Sankha, Sonu
    FLUID PHASE EQUILIBRIA, 2008, 266 (1-2) : 54 - 58
12345