Cu(I)-Catalyzed Synthesis of [60]Fullerene-Fused Lactams and Further Electrochemical Functionalization

被引：32
|
作者：
Liu, Zhan [1 ,2 ]
Yin, Zheng-Chun [1 ,2 ]
Lu, Wen-Qiang [1 ,2 ]
Niu, Chuang [1 ,2 ]
Chen, Muqing [4 ,5 ]
Yang, Shangfeng [4 ,5 ]
Wang, Guan-Wu [1 ,2 ,3 ]
机构：
[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
[4] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[5] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China
来源：
ORGANIC LETTERS | 2021年 / 23卷 / 10期
基金：
中国国家自然科学基金;
关键词：
REGIOSELECTIVE ELECTROSYNTHESIS; C-60;
D O I：
10.1021/acs.orglett.1c01269
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and efficient Cu(I)-catalyzed radical heteroannulation reaction of [60]fullerene (C-60) with alpha-bromo acetamides has been disclosed for the direct synthesis of diverse C-60-fused lactams. Furthermore, the formed C-60-fused lactams can be served as a versatile platform for further electrochemical functionalization to prepare 1,2-, 1,4-, 1,2,3,16-, and 1,4,9,25-adducts of C-60. In addition, a representative fullerene product has been applied as an overcoating layer of the electron-transporting layer in n-type perovskite solar cell.
引用
收藏
页码：4051 / 4056
页数：6
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