A thermal spin transition in a nanoporous iron(II) coordination framework material

被引：104

作者：

Neville, Suzanne M.

Moubaraki, Boujemaa

Murray, Keith S.

Kepert, Cameron J. ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

host-guest systems; iron; metal-organic framework; microporous materials; spin crossover;

D O I：

10.1002/anie.200603977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Influential guests: An abrupt spin-crossover transition is exhibited by a nanoporous framework material that consists of interpenetrated two-dimensional grids linked by hydrogen-bonding interactions. Desorption of guest molecules from the highly robust host lattice occurs by a single-crystal-to-single-crystal transformation and leads to subtle changes in the framework structure and spin-crossover properties. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2059 / 2062

页数：4

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