A thermal spin transition in a nanoporous iron(II) coordination framework material

被引：104
|
作者：
Neville, Suzanne M.
Moubaraki, Boujemaa
Murray, Keith S.
Kepert, Cameron J. [1 ]
机构：
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
[2] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期
关键词：
host-guest systems; iron; metal-organic framework; microporous materials; spin crossover;
D O I：
10.1002/anie.200603977
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Influential guests: An abrupt spin-crossover transition is exhibited by a nanoporous framework material that consists of interpenetrated two-dimensional grids linked by hydrogen-bonding interactions. Desorption of guest molecules from the highly robust host lattice occurs by a single-crystal-to-single-crystal transformation and leads to subtle changes in the framework structure and spin-crossover properties. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2059 / 2062
页数：4
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