Continuous-flow synthesis of polymer nanoparticles in a microreactor via miniemulsion photopolymerization

被引：28
|
作者：
Lobry, Emeline [1 ]
Jasinski, Florent [1 ]
Penconi, Marta [2 ]
Chemtob, Abraham [1 ]
Croutxe-Barghorn, Celine [1 ]
Oliveros, Esther [2 ]
Braun, Andre M. [3 ]
Criqui, Adrien [4 ]
机构：
[1] Univ Haute Alsace, ENSCMu, Lab Macromol Photochem & Engn, F-68093 Mulhouse, France
[2] Univ Toulouse 3, Paul Sabatier UPS, UMR CNRS 5623, Lab IMRCP, F-31062 Toulouse 9, France
[3] Karlsruhe Inst Technol, Engler Bunte Inst, D-76131 Karlsruhe, Germany
[4] Mader Res MADER Grp, F-68200 Mulhouse, France
来源：
RSC ADVANCES | 2014年 / 4卷 / 82期
关键词：
THIOL-ENE PHOTOPOLYMERIZATION; MONOMER MINIEMULSIONS; REACTORS; TEMPERATURE; PARTICLES; CHEMISTRY; ACRYLATE; DESIGN; SIZE;
D O I：
10.1039/c4ra06814a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient continuous synthesis of nanolatex was achieved in water using a single-lane photochemical microreactor combined with an energy-saving and safe UV fluorescent lamp. Acrylate and thiol-ene miniemulsions were polymerized in high yields at low irradiance (3mW cm(-2)) upon controlling droplet size, temperature and residence time.
引用
收藏
页码：43756 / 43759
页数：4
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