A new fluorescent and colorimetric chemosensor for Al3+ and F-/CN- based on a julolidine unit and its bioimaging in living cells

被引:42
|
作者
Liu, Fangfang [1 ]
Fan, Congbin [1 ]
Tu, Yayi [1 ]
Pu, Shouzhi [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Jiangxi, Peoples R China
来源
RSC ADVANCES | 2018年 / 8卷 / 54期
基金
中国国家自然科学基金;
关键词
DUAL-CHANNEL DETECTION; TURN-ON CHEMOSENSOR; SCHIFF-BASE; AQUEOUS-SOLUTION; SELECTIVE RECOGNITION; ALUMINUM ION; CYANIDE IONS; FLUORIDE-ION; PROBE; SENSOR;
D O I
10.1039/c8ra05439h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel multifunctional chemosensor HL bearing a julolidine unit and a Schiff base unit has been synthesized. As a fluorescent sensor, HL exhibited excellent selectivity and high sensitivity to Al3+ and F-/CN- with a low detection limit in acetonitrile. Moreover, HL also showed good colorimetric selectivity to F-/CN-; a solution color change from colorless to light yellow in acetonitrile was observed by the naked-eye'. The properties of HL with Al3+ and F-/CN- were studied by UV-vis absorption spectroscopy, fluorescence spectroscopy, high-resolution mass spectrometry and H-1 NMR titration. Furthermore, the cell imaging experimental results indicated that the chemosensor HL could be applied for the detection of Al3+ in living cells.
引用
收藏
页码:31113 / 31120
页数:8
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