Bis(μ-phenylphosphido-κ2P:P)bis{[1,2-(dicyclohexylphosphino)ethane-κ2P,P′]platinum(I)} dichloride bis(dichloromethane) hexane solvate

被引：1
|
作者：
Jaska, CA [1 ]
Lough, AJ [1 ]
Manners, I [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804025309
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Pt-2(C6H6P)(2)(C26H48P2)(2)]Cl-2.2CH(2)Cl(2).C6H14, the cation crystallizes as a phosphido-bridged Pt-I dimer [Pt(dcype)(mu-PPhH)](2)Cl-2, with crystallographic 2/m symmetry [dcype is 1,2-bis(dicyclohexylphosphino)ethane]. The Pt2P2 core forms a planar distorted square capped by chelating bisphosphine ligands, resulting in a distorted square-planar geometry for the Pt atoms. In the Pt2P2 core, the Pt-P bond length is 2.3403 (9) Angstrom, with a narrow P-Pt-P angle of 76.87 (6)degrees and a wide Pt-P-Pt angle of 103.13 (6)degrees. The bite angle of the dcype ligand is 85.70 (6)degrees, with a Pt-P bond length of 2.2993 (11)degrees.
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收藏
页码：M1653 / M1655
页数：3
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