Continuity Control of b-Oriented MFI Zeolite Films by Microwave Synthesis

被引：36
|
作者：
Li, Xianming [1 ]
Yan, Yushan [1 ,2 ]
Wang, Zhengbao [1 ]
机构：
[1] Zhejiang Univ, Dept Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Univ Calif Riverside, Dept Chem & Environm Engn, Riverside, CA 92521 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2010年 / 49卷 / 12期
基金：
中国博士后科学基金; 浙江省自然科学基金;
关键词：
ASSISTED HYDROTHERMAL SYNTHESIS; IN-SITU CRYSTALLIZATION; THIN-FILMS; SECONDARY GROWTH; RAPID SYNTHESIS; MEMBRANES; ORIENTATION; FABRICATION;
D O I：
10.1021/ie1000136
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Influences of aging and crystallization conditions on the continuity of b-oriented MFI zeolite films on stainless steel substrates are systematically investigated. A long aging time (e.g., 20 h) at room temperature is needed to obtain a continuous b-oriented MFI zeolite film by the microwave heating at 165 degrees C. However, the aging time can be shortened from 20 h to 30 min by elevating the aging temperature to 80 degrees C. Compared with the conventional heating (2 h), continuous b-oriented MFI zeolite films are prepared on stainless steel substrates with a much shorter crystallization time by the microwave heating (35 min). Continuous b-oriented MFI zeolite films can be synthesized by controlling nuclei concentration and crystal size, which are mainly determined by the conditions of the aging and crystallization respectively. On the basis of the results from these experiments, a film continuity-synthesis condition map is obtained and a film formation mechanism is discussed.
引用
收藏
页码：5933 / 5938
页数：6
相关论文
共 50 条
  • [21] Molecular sieving in a nanoporous b-oriented pure-silica-zeolite MFI monocrystal film
    Li, S
    Wang, X
    Beving, D
    Chen, ZW
    Yan, YS
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (13) : 4122 - 4123
  • [22] Rapid fabrication of highly b-oriented zeolite MFI thin films using ammonium salts as crystallization-mediating agents
    Lu, Xiaofei
    Peng, Yong
    Wang, Zhengbao
    Yan, Yushan
    CHEMICAL COMMUNICATIONS, 2015, 51 (55) : 11076 - 11079
  • [23] Twin suppression effect of dihydroxy-benzene isomers during the secondary growth of b-oriented zeolite MFI nanosheet films
    Xu, Ruilan
    Peng, Yong
    Lu, Peng
    Miao, Yurun
    Duan, Xuekui
    Lee, Dennis T. T.
    Wang, Rui
    Wang, Zhengbao
    Tsapatsis, Michael
    CRYSTENGCOMM, 2023, 25 (16) : 2359 - 2365
  • [24] Preparation of b-oriented MFI zeolite membranes on porous α-alumina substrates precoated with mesoporous silica sublayer
    Zhang, FZ
    Fuji, M
    Takahashi, M
    JOURNAL OF MATERIALS SCIENCE, 2005, 40 (9-10) : 2729 - 2732
  • [25] Preparation of b-oriented MFI zeolite membranes on porous α-alumina substrates precoated with mesoporous silica sublayer
    F. Z. Zhang
    M. Fuji
    M. Takahashi
    Journal of Materials Science, 2005, 40 : 2729 - 2732
  • [26] Fabrication of a Highly b-Oriented MFI-Type Zeolite Film by the Langmuir-Blodgett Method
    Wang, Zheng
    Yu, Ting
    Nian, Pei
    Zhang, Qingchun
    Yao, Junkang
    Li, Shan
    Gao, Zuoning
    Yue, Xianglong
    LANGMUIR, 2014, 30 (16) : 4531 - 4534
  • [27] Highly selective thin B-oriented MFI zeolite membranes on scalable modified stainless steel supports
    Banihashemi, Fateme
    Lai, Wen-Hsiung
    Lin, Jerry Y. S.
    JOURNAL OF MEMBRANE SCIENCE, 2025, 713
  • [28] A facile fabrication of highly b-oriented MFI zeolite films in the TEOS-TPAOH-H2O system without additives
    Lu, Xiaofei
    Peng, Yong
    Wang, Zhengbao
    Yan, Yushan
    MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 230 : 49 - 57
  • [29] Synthesis of oriented zeolite MFI films by solid-state transformation
    Nishide, T
    Hamatsu, T
    Kiyozumi, Y
    Mizukami, F
    JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (05) : 1465 - 1468
  • [30] Fabrication of highly b-oriented MFI monolayers on various substrates
    Liu, Yi
    Li, Yanshuo
    Yang, Weishen
    CHEMICAL COMMUNICATIONS, 2009, (12) : 1520 - 1522
12345